According to the Recapy context for The Score, their one-night stand becomes more because Allie—coming out of a breakup—wants to be just friends after the hook-up, but Dean refuses to let it end there. He pursues her hard instead of accepting a casual arrangement. Then some major life-changing events happen that force Dean to rethink his playboy priorities; as he pursues Allie and reassesses what he really wants, his pursuit turns into genuine feelings and they move beyond a one-night stand into a real relationship.
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